USAP-DC

{"dp_type": "Project", "free_text": "Ch4"}

[{"awards": "1643355 Steig, Eric; 1643394 Buizert, Christo", "bounds_geometry": "POLYGON((-180 -60,-144 -60,-108 -60,-72 -60,-36 -60,0 -60,36 -60,72 -60,108 -60,144 -60,180 -60,180 -63,180 -66,180 -69,180 -72,180 -75,180 -78,180 -81,180 -84,180 -87,180 -90,144 -90,108 -90,72 -90,36 -90,0 -90,-36 -90,-72 -90,-108 -90,-144 -90,-180 -90,-180 -87,-180 -84,-180 -81,-180 -78,-180 -75,-180 -72,-180 -69,-180 -66,-180 -63,-180 -60))", "dataset_titles": "Antarctica 40,000 Year Temperature and Elevation Reconstructions; Layer and Thinning based Accumulation Rate Reconstructions; WAIS Divide 67-6ka nssS Data and EDML, EDC and TALDICE Volcanic Tie Points", "datasets": [{"dataset_uid": "200220", "doi": "", "keywords": null, "people": null, "repository": "NCEI", "science_program": null, "title": "WAIS Divide 67-6ka nssS Data and EDML, EDC and TALDICE Volcanic Tie Points", "url": "https://www.ncdc.noaa.gov/paleo/study/24530"}, {"dataset_uid": "601448", "doi": "10.15784/601448", "keywords": "Antarctica; Glaciers/ice Sheet; Glaciers/Ice Sheet; Glaciology; Ice Core Records; Snow/ice; Snow/Ice", "people": "Fudge, T. J.", "repository": "USAP-DC", "science_program": null, "title": "Layer and Thinning based Accumulation Rate Reconstructions", "url": "https://www.usap-dc.org/view/dataset/601448"}, {"dataset_uid": "200219", "doi": "", "keywords": null, "people": null, "repository": "NCEI", "science_program": null, "title": "Antarctica 40,000 Year Temperature and Elevation Reconstructions", "url": "https://www.ncdc.noaa.gov/paleo-search/study/32632"}], "date_created": "Fri, 28 May 2021 00:00:00 GMT", "description": "The main objectives of the proposed work are twofold: (1) to fully characterize the timing and spatial pattern of millennial-scale Antarctic climate change during the deglaciation and Dansgaard-Oeschger (DO) cycles using multiple synchronized Antarctic ice cores; (2) to provide state-of-the-art, internally-consistent ice core chronologies for all US Antarctic ice cores. The WAIS Divide, Siple Dome, Byrd, Taylor Dome and South Pole ice cores will be synchronized using volcanic, dust and gas (CH4 and d18Oatm) markers; this synchronization will be combined with ice-flow and firn densification modeling to create gas-age and ice-age scales for these ice cores, consistent with the highly accurate WAIS Divide chronology. The grant will support ongoing efforts to synchronize the WAIS Divide core to the Dome C and Dronning Maud Land cores, which in turn have been synchronized to several East Antarctic ice cores. Using this chronological framework, the interpolar phasing of millennial-scale climate change will be investigated during the DO cycles using 6 Antarctic ice cores, and during the last deglaciation using 11 ice cores. The relationship between accumulation rate and site temperature during the natural warming of the last deglaciation will be investigated for all the Antarctic ice cores included in the framework.", "east": 180.0, "geometry": "POINT(0 -89.999)", "instruments": null, "is_usap_dc": true, "keywords": "GLACIERS/ICE SHEETS; Antarctica", "locations": "Antarctica", "north": -60.0, "nsf_funding_programs": "Antarctic Glaciology; Antarctic Glaciology", "paleo_time": null, "persons": "Fudge, T. J.; Steig, Eric J.; Buizert, Christo", "platforms": null, "repo": "NCEI", "repositories": "NCEI; USAP-DC", "science_programs": null, "south": -90.0, "title": "Collaborative Research: The Timing and Spatial Expression of the Bipolar Seesaw", "uid": "p0010183", "west": -180.0}, {"awards": "1443470 Aydin, Murat", "bounds_geometry": "POLYGON((-180 -60,-144 -60,-108 -60,-72 -60,-36 -60,0 -60,36 -60,72 -60,108 -60,144 -60,180 -60,180 -63,180 -66,180 -69,180 -72,180 -75,180 -78,180 -81,180 -84,180 -87,180 -90,144 -90,108 -90,72 -90,36 -90,0 -90,-36 -90,-72 -90,-108 -90,-144 -90,-180 -90,-180 -87,-180 -84,-180 -81,-180 -78,-180 -75,-180 -72,-180 -69,-180 -66,-180 -63,-180 -60))", "dataset_titles": "South Pole ice core (SPC14) discrete methane data; SP19 Gas Chronology; SPC14 carbonyl sulfide, methyl chloride, and methyl bromide measurements from South Pole, Antarctica", "datasets": [{"dataset_uid": "601270", "doi": "10.15784/601270", "keywords": "Antarctica", "people": "Aydin, Murat", "repository": "USAP-DC", "science_program": "SPICEcore", "title": "SPC14 carbonyl sulfide, methyl chloride, and methyl bromide measurements from South Pole, Antarctica", "url": "https://www.usap-dc.org/view/dataset/601270"}, {"dataset_uid": "601381", "doi": "10.15784/601381", "keywords": "Antarctica; Ch4; Glaciers/ice Sheet; Glaciers/Ice Sheet; Glaciology; Ice Core Data; Ice Core Records; Methane; South Pole; SPICEcore", "people": "Kreutz, Karl; Severinghaus, Jeffrey P.; Epifanio, Jenna; Brook, Edward J.; Buizert, Christo; Aydin, Murat; Edwards, Jon S.; Sowers, Todd A.; Kahle, Emma; Steig, Eric J.; Winski, Dominic A.; Osterberg, Erich; Fudge, T. J.; Hood, Ekaterina; Kalk, Michael; Ferris, David G.; Kennedy, Joshua A.", "repository": "USAP-DC", "science_program": "SPICEcore", "title": "South Pole ice core (SPC14) discrete methane data", "url": "https://www.usap-dc.org/view/dataset/601381"}, {"dataset_uid": "601380", "doi": "10.15784/601380", "keywords": "Antarctica; Ch4; Glaciers/ice Sheet; Glaciers/Ice Sheet; Glaciology; Ice Core Records; Ice Core Stratigraphy; Methane; South Pole; SPICEcore", "people": "Epifanio, Jenna", "repository": "USAP-DC", "science_program": "SPICEcore", "title": "SP19 Gas Chronology", "url": "https://www.usap-dc.org/view/dataset/601380"}], "date_created": "Thu, 26 Mar 2020 00:00:00 GMT", "description": "In the past, Earth\u0027s climate underwent dramatic changes that influenced physical, chemical, geological, and biological processes on a global scale. Such changes left an imprint in Earth\u0027s atmosphere, as shown by the variability in abundances of trace gases like carbon dioxide and methane. In return, changes in the atmospheric trace gas composition affected Earth\u0027s climate. Studying compositional variations of the past atmosphere helps us understand the history of interactions between global biogeochemical cycles and Earth?s climate. The most reliable information on past atmospheric composition comes from analysis of air entrapped in polar ice cores. This project aims to generate ice-core records of relatively short-lived, very-low-abundance trace gases to determine the range of past variability in their atmospheric levels and investigate the changes in global biogeochemical cycles that caused this variability. This project measures three such gases: carbonyl sulfide, methyl chloride, and methyl bromide. Changes in carbonyl sulfide can indicate changes in primary productivity and photosynthetic update of carbon dioxide. Changes in methyl chloride and methyl bromide significantly impact natural variability in stratospheric ozone. In addition, the processes that control atmospheric levels of methyl chloride and methyl bromide are shared with those controlling levels of atmospheric methane. The measurements will be made in the new ice core from the South Pole, which is expected to provide a 40,000-year record.\u003cbr/\u003e\u003cbr/\u003eThe primary focus of this project is to develop high-quality trace gas records for the entire Holocene period (the past 11,000 years), with additional, more exploratory measurements from the last glacial period including the period from 29,000-36,000 years ago when there were large changes in atmospheric methane. Due to the cold temperatures of the South Pole ice, the proposed carbonyl sulfide measurements are expected to provide a direct measure of the past atmospheric variability of this gas without the large hydrolysis corrections that are necessary for interpretation of measurements from ice cores in warmer settings. Furthermore, we will test the expectation that contemporaneous measurements from the last glacial period in the deep West Antarctic Ice Sheet Divide ice core will not require hydrolysis loss corrections. With respect to methyl chloride, we aim to verify and improve the existing Holocene atmospheric history from the Taylor Dome ice core in Antarctica. The higher resolution of our measurements compared with those from Taylor Dome will allow us to derive a more statistically significant relationship between methyl chloride and methane. With respect to methyl bromide, we plan to extend the existing 2,000-year database to 11,000 years. Together, the methyl bromide and methyl chloride records will provide strong measurement-based constraints on the natural variability of stratospheric halogens during the Holocene period. In addition, the methyl bromide record will provide insight into the correlation between methyl chloride and methane during the Holocene period due to common sources and sinks.", "east": 180.0, "geometry": "POINT(0 -89.999)", "instruments": "NOT APPLICABLE \u003e NOT APPLICABLE \u003e NOT APPLICABLE", "is_usap_dc": true, "keywords": "NOT APPLICABLE; CARBONYL SULFIDE; HALOCARBONS AND HALOGENS; TRACE GASES/TRACE SPECIES; Antarctic; USAP-DC", "locations": "Antarctic", "north": -60.0, "nsf_funding_programs": "Antarctic Glaciology", "paleo_time": null, "persons": "Aydin, Murat", "platforms": "OTHER \u003e NOT APPLICABLE \u003e NOT APPLICABLE", "repo": "USAP-DC", "repositories": "USAP-DC", "science_programs": null, "south": -90.0, "title": "Carbonyl Sulfide, Methyl Chloride, and Methyl Bromide Measurements in the New Intermediate-depth South Pole Ice Core", "uid": "p0010089", "west": -180.0}, {"awards": "1443105 Steig, Eric", "bounds_geometry": "POINT(0 -90)", "dataset_titles": "Continuous-flow measurements of the complete water isotope ratios (D/H, 17O/16O, 18O/16) from the South Pole ice core; South Pole high resolution ice core water stable isotope record for dD, d18O; South Pole Ice Core Holocene Major Ion Dataset; SP19 Gas Chronology; Temperature, accumulation rate, and layer thinning from the South Pole ice core (SPC14)", "datasets": [{"dataset_uid": "601399", "doi": "10.15784/601399", "keywords": "Antarctica; Glaciology; Ice Core; Ice Core Chemistry; Ice Core Records; Major Ion; Sea Ice; Sea Salt; Sodium; South Pole; SPICEcore", "people": "Winski, Dominic A.", "repository": "USAP-DC", "science_program": "SPICEcore", "title": "South Pole Ice Core Holocene Major Ion Dataset", "url": "https://www.usap-dc.org/view/dataset/601399"}, {"dataset_uid": "601239", "doi": "10.15784/601239", "keywords": "Antarctica; Cavity Ring Down Spectrometers; Delta 18O; Delta Deuterium; Deuterium Isotopes; Glaciers/ice Sheet; Glaciers/Ice Sheet; Glaciology; Ice; Ice Core; Ice Core Chemistry; Ice Core Data; Oxygen Isotope; Snow/ice; Snow/Ice; Stable Isotopes", "people": "Kahle, Emma; Steig, Eric J.; Jones, Tyler R.; Schauer, Andrew; White, James; Morris, Valerie; Vaughn, Bruce", "repository": "USAP-DC", "science_program": "SPICEcore", "title": "South Pole high resolution ice core water stable isotope record for dD, d18O", "url": "https://www.usap-dc.org/view/dataset/601239"}, {"dataset_uid": "601429", "doi": "10.15784/601429", "keywords": "Antarctica; Climate; Deuterium; Glaciers/ice Sheet; Glaciers/Ice Sheet; Glaciology; Hydrogen; Ice; Ice Core; Ice Core Chemistry; Oxygen; Paleoclimate; Snow/ice; Snow/Ice; South Pole; Stable Isotopes", "people": "Vaughn, Bruce; White, James; Morris, Valerie; Schauer, Andrew; Kahle, Emma; Jones, Tyler R.; Steig, Eric J.", "repository": "USAP-DC", "science_program": "SPICEcore", "title": "Continuous-flow measurements of the complete water isotope ratios (D/H, 17O/16O, 18O/16) from the South Pole ice core", "url": "https://www.usap-dc.org/view/dataset/601429"}, {"dataset_uid": "601380", "doi": "10.15784/601380", "keywords": "Antarctica; Ch4; Glaciers/ice Sheet; Glaciers/Ice Sheet; Glaciology; Ice Core Records; Ice Core Stratigraphy; Methane; South Pole; SPICEcore", "people": "Epifanio, Jenna", "repository": "USAP-DC", "science_program": "SPICEcore", "title": "SP19 Gas Chronology", "url": "https://www.usap-dc.org/view/dataset/601380"}, {"dataset_uid": "601396", "doi": "10.15784/601396", "keywords": "Accumulation; Antarctica; Diffusion Length; Glaciers/ice Sheet; Glaciers/Ice Sheet; Glaciology; Ice Core Records; Ice Dynamic; Layer Thinning; Oxygen Isotope; South Pole; SPICEcore; Temperature", "people": "Waddington, Edwin D.; White, James; Schauer, Andrew; Vaughn, Bruce; Epifanio, Jenna; Buizert, Christo; Morris, Valerie; Koutnik, Michelle; Fudge, T. J.; Jones, Tyler R.; Steig, Eric J.; Kahle, Emma; Conway, Howard; Stevens, Max", "repository": "USAP-DC", "science_program": "SPICEcore", "title": "Temperature, accumulation rate, and layer thinning from the South Pole ice core (SPC14)", "url": "https://www.usap-dc.org/view/dataset/601396"}], "date_created": "Sun, 17 Nov 2019 00:00:00 GMT", "description": "This project will develop a record of the stable-isotope ratios of water from an ice core at the South Pole, Antarctica. Water-isotope ratio measurements provide a means to determine variability in temperature through time. South Pole is distinct from most other locations in Antarctica in showing no warming in recent decades, but little is known about temperature variability in this location prior to the installation of weather stations in 1957. The measurements made as part of this project will result in a much longer temperature record, extending at least 40,000 years, aiding our ability to understand what controls Antarctic climate, and improving projections of future Antarctic climate change. Data from this project will be critical to other investigators working on the South Pole ice core, and of general interest to other scientists and the public. Data will be provided rapidly to other investigators and made public as soon as possible.\u003cbr/\u003e\u003cbr/\u003eThis project will obtain records of the stable-isotope ratios of water on the ice core currently being obtained at South Pole. The core will reach a depth of 1500 m and an age of 40,000 years. The project will use laser spectroscopy to obtain both an ultra-high-resolution record of oxygen 18/16 and deuterium-hydrogen ratios, and a lower-resolution record of oxygen 17/16 ratios. The high-resolution measurements will be used to aid in dating the core, and to provide estimates of isotope diffusion that constrain the process of firn densification. The novel 17/16 measurement provides additional constraints on the isotope fractionation due to the temperature-dependent supersaturation ratio, which affects the fractionation of water during the liquid-solid condensate transition. Together, these techniques will allow for improved accuracy in the use of the water isotope ratios as proxies for ice-sheet temperature, sea-surface temperature, and atmospheric circulation. The result will be a record of decadal through centennial and millennial scale climate change in a climatically distinct region in East Antarctica that has not been previously sampled by deep ice coring. The project will support a graduate student who will be co-advised by faculty at the University of Washington and the University of Colorado, and will be involved in all aspects of the work.", "east": 0.0, "geometry": "POINT(0 -90)", "instruments": "IN SITU/LABORATORY INSTRUMENTS \u003e SPECTROMETERS/RADIOMETERS \u003e MASS SPECTROMETERS", "is_usap_dc": true, "keywords": "SPICEcore; D18O; LABORATORY; OXYGEN ISOTOPE ANALYSIS; Oxygen Isotope; South Pole; USAP-DC; GLACIERS/ICE SHEETS; Antarctica; AMD; FIELD INVESTIGATION; Ice Core", "locations": "Antarctica; South Pole", "north": -90.0, "nsf_funding_programs": "Antarctic Glaciology", "paleo_time": "PHANEROZOIC \u003e CENOZOIC \u003e QUATERNARY \u003e HOLOCENE", "persons": "Steig, Eric J.; White, James", "platforms": "LAND-BASED PLATFORMS \u003e FIELD SITES \u003e FIELD INVESTIGATION; OTHER \u003e PHYSICAL MODELS \u003e LABORATORY", "repo": "USAP-DC", "repositories": "USAP-DC", "science_programs": "SPICEcore", "south": -90.0, "title": "Collaborative Research: Record of the Triple-oxygen Isotope and Hydrogen Isotope Composition of Ice from an Ice Core at South Pole", "uid": "p0010065", "west": 0.0}, {"awards": "1142517 Aydin, Murat; 1142646 Twickler, Mark; 1141839 Steig, Eric", "bounds_geometry": "POINT(90 -90)", "dataset_titles": "South Pole Ice Core Holocene Major Ion Dataset; South Pole ice core (SPC14) discrete methane data; South Pole Ice Core (SPICEcore) SPC14 Core Quality Versus Depth; SP19 Gas Chronology; Temperature, accumulation rate, and layer thinning from the South Pole ice core (SPC14)", "datasets": [{"dataset_uid": "601399", "doi": "10.15784/601399", "keywords": "Antarctica; Glaciology; Ice Core; Ice Core Chemistry; Ice Core Records; Major Ion; Sea Ice; Sea Salt; Sodium; South Pole; SPICEcore", "people": "Winski, Dominic A.", "repository": "USAP-DC", "science_program": "SPICEcore", "title": "South Pole Ice Core Holocene Major Ion Dataset", "url": "https://www.usap-dc.org/view/dataset/601399"}, {"dataset_uid": "601396", "doi": "10.15784/601396", "keywords": "Accumulation; Antarctica; Diffusion Length; Glaciers/ice Sheet; Glaciers/Ice Sheet; Glaciology; Ice Core Records; Ice Dynamic; Layer Thinning; Oxygen Isotope; South Pole; SPICEcore; Temperature", "people": "Waddington, Edwin D.; White, James; Schauer, Andrew; Vaughn, Bruce; Epifanio, Jenna; Buizert, Christo; Morris, Valerie; Koutnik, Michelle; Fudge, T. J.; Jones, Tyler R.; Steig, Eric J.; Kahle, Emma; Conway, Howard; Stevens, Max", "repository": "USAP-DC", "science_program": "SPICEcore", "title": "Temperature, accumulation rate, and layer thinning from the South Pole ice core (SPC14)", "url": "https://www.usap-dc.org/view/dataset/601396"}, {"dataset_uid": "601221", "doi": "10.15784/601221", "keywords": "Antarctica; Glaciers/ice Sheet; Glaciers/Ice Sheet; Glaciology; Ice; Ice Core Data; Ice Core Depth; Ice Core Records; Snow/ice; Snow/Ice; SPICEcore", "people": "Aydin, Murat; Kahle, Emma; Nicewonger, Melinda R.; Fudge, T. J.; Hargreaves, Geoff; Nunn, Richard; Steig, Eric J.; Casey, Kimberly A.; Fegyveresi, John; Twickler, Mark; Souney, Joseph Jr.", "repository": "USAP-DC", "science_program": "SPICEcore", "title": "South Pole Ice Core (SPICEcore) SPC14 Core Quality Versus Depth", "url": "https://www.usap-dc.org/view/dataset/601221"}, {"dataset_uid": "601381", "doi": "10.15784/601381", "keywords": "Antarctica; Ch4; Glaciers/ice Sheet; Glaciers/Ice Sheet; Glaciology; Ice Core Data; Ice Core Records; Methane; South Pole; SPICEcore", "people": "Kreutz, Karl; Severinghaus, Jeffrey P.; Epifanio, Jenna; Brook, Edward J.; Buizert, Christo; Aydin, Murat; Edwards, Jon S.; Sowers, Todd A.; Kahle, Emma; Steig, Eric J.; Winski, Dominic A.; Osterberg, Erich; Fudge, T. J.; Hood, Ekaterina; Kalk, Michael; Ferris, David G.; Kennedy, Joshua A.", "repository": "USAP-DC", "science_program": "SPICEcore", "title": "South Pole ice core (SPC14) discrete methane data", "url": "https://www.usap-dc.org/view/dataset/601381"}, {"dataset_uid": "601380", "doi": "10.15784/601380", "keywords": "Antarctica; Ch4; Glaciers/ice Sheet; Glaciers/Ice Sheet; Glaciology; Ice Core Records; Ice Core Stratigraphy; Methane; South Pole; SPICEcore", "people": "Epifanio, Jenna", "repository": "USAP-DC", "science_program": "SPICEcore", "title": "SP19 Gas Chronology", "url": "https://www.usap-dc.org/view/dataset/601380"}], "date_created": "Wed, 30 Oct 2019 00:00:00 GMT", "description": "This proposal requests support for a project to drill and recover a new ice core from South Pole, Antarctica. The South Pole ice core will be drilled to a depth of 1500 m, providing an environmental record spanning approximately 40 kyrs. This core will be recovered using a new intermediate drill, which is under development by the U.S. Ice Drilling Design and Operations (IDDO) group in collaboration with Danish scientists. This proposal seeks support to provide: 1) scientific management and oversight for the South Pole ice core project, 2) personnel for ice core drilling and core processing, 3) data management, and 3) scientific coordination and communication via scientific workshops. The intellectual merit of the work is that the analysis of stable isotopes, atmospheric gases, and aerosol-borne chemicals in polar ice has provided unique information about the magnitude and timing of changes in climate and climate forcing through time. The international ice core research community has articulated the goal of developing spatial arrays of ice cores across Antarctica and Greenland, allowing the reconstruction of regional patterns of climate variability in order to provide greater insight into the mechanisms driving climate change. The broader impacts of the project include obtaining the South Pole ice core will support a wide range of ice core science projects, which will contribute to the societal need for a basic understanding of climate and the capability to predict climate and ice sheet stability on long time scales. Second, the project will help train the next generation of ice core scientists by providing the opportunity for hands-on field and core processing experience for graduate students and postdoctoral researchers. A postdoctoral researcher at the University of Washington will be directly supported by this project, and many other young scientists will interact with the project through individual science proposals. Third, the project will result in the development of a new intermediate drill which will become an important resource to US ice core science community. This drill will have a light logistical footprint which will enable a wide range of ice core projects to be carried out that are not currently feasible. Finally, although this project does not request funds for outreach activities, the project will run workshops that will encourage and enable proposals for coordinated outreach activities involving the South Pole ice core science team.", "east": 90.0, "geometry": "POINT(90 -90)", "instruments": "IN SITU/LABORATORY INSTRUMENTS \u003e CHEMICAL METERS/ANALYZERS \u003e GAS CHROMATOGRAPHS", "is_usap_dc": true, "keywords": "USAP-DC; Amd/Us; Antarctica; ANALYTICAL LAB; USA/NSF; AMD; South Pole; ICE CORE RECORDS; FIELD INVESTIGATION; Ice Core", "locations": "Antarctica; South Pole", "north": -90.0, "nsf_funding_programs": "Antarctic Glaciology; Antarctic Glaciology; Antarctic Glaciology", "paleo_time": null, "persons": "Twickler, Mark; Souney, Joseph Jr.; Aydin, Murat; Steig, Eric J.", "platforms": "LAND-BASED PLATFORMS \u003e FIELD SITES \u003e FIELD INVESTIGATION; OTHER \u003e PHYSICAL MODELS \u003e ANALYTICAL LAB", "repo": "USAP-DC", "repositories": "USAP-DC", "science_programs": "SPICEcore", "south": -90.0, "title": "Collaborative Research: A 1500m Ice Core from South Pole", "uid": "p0010060", "west": 90.0}, {"awards": "1443397 Kreutz, Karl; 1443663 Cole-Dai, Jihong; 1443336 Osterberg, Erich", "bounds_geometry": "POINT(-180 -90)", "dataset_titles": "Preliminary SPC14 high-resolution Fe and Mn biologically relevant and dissolved trace metal concentrations spanning -42 \u2013 54,300 years BP.; South Pole Ice Core Holocene Major Ion Dataset; South Pole Ice Core Sea Salt and Major Ions; South Pole ice core (SPC14) discrete methane data; South Pole (SPC14) microparticle concentration, mass concentration, flux, particle-size-distribution mode, and aspect ratio measurements; SPICEcore 400-480 m Major Ions SDSU; The South Pole Ice Core (SPICEcore) chronology and supporting data", "datasets": [{"dataset_uid": "601206", "doi": "10.15784/601206", "keywords": "Antarctica; Calcium (ca); Chemistry:ice; Chemistry:Ice; Depth; Glaciers/ice Sheet; Glaciers/Ice Sheet; Glaciochemistry; Glaciology; Ice; Ice Core; Ice Core Chemistry; Ice Core Data; Ice Core Records; Ice Core Stratigraphy; Nitrate; Nitrogen Isotopes; Paleoclimate; Snow/ice; Snow/Ice; South Pole; SPICEcore", "people": "Ferris, David G.; Aydin, Murat; Nicewonger, Melinda R.; Casey, Kimberly A.; Alley, Richard; Waddington, Edwin D.; Jones, Tyler R.; Iverson, Nels; Buizert, Christo; Osterberg, Erich; Dunbar, Nelia; Fudge, T. J.; Steig, Eric J.; Morris, Valerie; Kahle, Emma; Bay, Ryan; Souney, Joseph Jr.; Sigl, Michael; McConnell, Joseph; Fegyveresi, John; Cole-Dai, Jihong; Thundercloud, Zayta; Cox, Thomas S.; Kreutz, Karl; Epifanio, Jenna; Severinghaus, Jeffrey P.; Ortman, Nikolas; Brook, Edward J.; Beaudette, Ross; Sowers, Todd A.; Winski, Dominic A.", "repository": "USAP-DC", "science_program": "SPICEcore", "title": "The South Pole Ice Core (SPICEcore) chronology and supporting data", "url": "https://www.usap-dc.org/view/dataset/601206"}, {"dataset_uid": "601675", "doi": "10.15784/601675", "keywords": "Antarctica; South Pole; SPICEcore", "people": "Kreutz, Karl", "repository": "USAP-DC", "science_program": "SPICEcore", "title": "Preliminary SPC14 high-resolution Fe and Mn biologically relevant and dissolved trace metal concentrations spanning -42 \u2013 54,300 years BP.", "url": "https://www.usap-dc.org/view/dataset/601675"}, {"dataset_uid": "601381", "doi": "10.15784/601381", "keywords": "Antarctica; Ch4; Glaciers/ice Sheet; Glaciers/Ice Sheet; Glaciology; Ice Core Data; Ice Core Records; Methane; South Pole; SPICEcore", "people": "Kreutz, Karl; Severinghaus, Jeffrey P.; Epifanio, Jenna; Brook, Edward J.; Buizert, Christo; Aydin, Murat; Edwards, Jon S.; Sowers, Todd A.; Kahle, Emma; Steig, Eric J.; Winski, Dominic A.; Osterberg, Erich; Fudge, T. J.; Hood, Ekaterina; Kalk, Michael; Ferris, David G.; Kennedy, Joshua A.", "repository": "USAP-DC", "science_program": "SPICEcore", "title": "South Pole ice core (SPC14) discrete methane data", "url": "https://www.usap-dc.org/view/dataset/601381"}, {"dataset_uid": "601430", "doi": "10.15784/601430", "keywords": "Antarctica; Ions; South Pole; SPICEcore", "people": "Cole-Dai, Jihong; Larrick, Carleigh", "repository": "USAP-DC", "science_program": "SPICEcore", "title": "SPICEcore 400-480 m Major Ions SDSU", "url": "https://www.usap-dc.org/view/dataset/601430"}, {"dataset_uid": "601553", "doi": "10.15784/601553", "keywords": "Antarctica; Dust; Ice Core; South Pole", "people": "Kreutz, Karl", "repository": "USAP-DC", "science_program": "SPICEcore", "title": "South Pole (SPC14) microparticle concentration, mass concentration, flux, particle-size-distribution mode, and aspect ratio measurements", "url": "https://www.usap-dc.org/view/dataset/601553"}, {"dataset_uid": "601754", "doi": "10.15784/601754", "keywords": "Antarctica; Glaciology; Ice Core; Ice Core Chemistry; Ice Core Records; Major Ion; Sea Ice; Sea Salt; Sodium; South Pole; SPICEcore", "people": "Winski, Dominic A.", "repository": "USAP-DC", "science_program": "SPICEcore", "title": "South Pole Ice Core Sea Salt and Major Ions", "url": "https://www.usap-dc.org/view/dataset/601754"}, {"dataset_uid": "601399", "doi": "10.15784/601399", "keywords": "Antarctica; Glaciology; Ice Core; Ice Core Chemistry; Ice Core Records; Major Ion; Sea Ice; Sea Salt; Sodium; South Pole; SPICEcore", "people": "Winski, Dominic A.", "repository": "USAP-DC", "science_program": "SPICEcore", "title": "South Pole Ice Core Holocene Major Ion Dataset", "url": "https://www.usap-dc.org/view/dataset/601399"}], "date_created": "Thu, 29 Aug 2019 00:00:00 GMT", "description": "This collaborative project explores the signatures and causes of natural climate change in the region surrounding Antarctica over the last 40,000 years as the Earth transitioned from an ice age into the modern warm period. The researchers will investigate how the wind belts that surround Antarctica changed in their strength and position through time, and document explosive volcanic eruptions and CO2 cycling in the Southern Ocean as potential climate forcing mechanisms over this interval. Understanding how and why the climate varied naturally in the past is critical for improving understanding of modern climate change and projections of future climate under higher levels of atmospheric CO2. \u003cbr/\u003e\u003cbr/\u003eThe investigators plan to conduct a suite of chemical measurements along the 1500m length of the South Pole Ice Core, including major ion and trace element concentrations, and microparticle (dust) concentrations and size distributions. These measurements will (1) extend the South Pole record of explosive volcanic eruptions to 40,000 years using sulfate and particle data; (2) establish the relative timing of climate changes in dust source regions of Patagonia, New Zealand, and Australia using dust flux data; (3) investigate changes in the strength and position of the westerly wind belt using dust size distribution data; and (4) quantify the flux of bioavailable trace metals deposited as dust to the Southern Ocean over time. These chemistry records will also be critical for creating the timescale that will be used by all researchers studying records from the South Pole core. The project will support four graduate students and several undergraduate students across three different institutions, and become a focus of the investigators\u0027 efforts to disseminate outcomes of climate change science to the broader community.", "east": -180.0, "geometry": "POINT(-180 -90)", "instruments": null, "is_usap_dc": true, "keywords": "Antarctica; ICE CORE RECORDS; USAP-DC; Amd/Us; USA/NSF; LABORATORY; AMD", "locations": "Antarctica", "north": -90.0, "nsf_funding_programs": "Antarctic Glaciology; Antarctic Glaciology; Antarctic Glaciology", "paleo_time": null, "persons": "Osterberg, Erich", "platforms": "OTHER \u003e PHYSICAL MODELS \u003e LABORATORY", "repo": "USAP-DC", "repositories": "USAP-DC", "science_programs": "SPICEcore", "south": -90.0, "title": "Collaborative Research: South Pole Ice Core Chronology and Climate Records using Chemical and Microparticle Measurements", "uid": "p0010051", "west": -180.0}, {"awards": "1443710 Severinghaus, Jeffrey; 1443472 Brook, Edward; 1443464 Sowers, Todd", "bounds_geometry": "POINT(0 -90)", "dataset_titles": "South Pole CH4 data for termination; South Pole Ice Core Isotopes of N2 and Ar; South Pole ice core (SPC14) discrete methane data; South Pole ice core total air content; South Pole (SPICECORE) 15N, 18O, O2/N2 and Ar/N2; SP19 Gas Chronology", "datasets": [{"dataset_uid": "601380", "doi": "10.15784/601380", "keywords": "Antarctica; Ch4; Glaciers/ice Sheet; Glaciers/Ice Sheet; Glaciology; Ice Core Records; Ice Core Stratigraphy; Methane; South Pole; SPICEcore", "people": "Epifanio, Jenna", "repository": "USAP-DC", "science_program": "SPICEcore", "title": "SP19 Gas Chronology", "url": "https://www.usap-dc.org/view/dataset/601380"}, {"dataset_uid": "601152", "doi": "10.15784/601152", "keywords": "Antarctica; Antarctic Ice Sheet; Chemistry:gas; Chemistry:Gas; Chemistry:ice; Chemistry:Ice; Delta 18O; Dole Effect; Firn Thickness; Gas Isotopes; Geochemistry; Glaciers/ice Sheet; Glaciers/Ice Sheet; Glaciology; Gravitational Settling; Ice; Ice Core Chemistry; Ice Core Data; Ice Core Gas Records; Ice Core Records; Inert Gases; Nitrogen; Nitrogen Isotopes; Oxygen; Oxygen Isotope; Snow/ice; Snow/Ice; South Pole; SPICEcore", "people": "Severinghaus, Jeffrey P.", "repository": "USAP-DC", "science_program": "SPICEcore", "title": "South Pole (SPICECORE) 15N, 18O, O2/N2 and Ar/N2", "url": "https://www.usap-dc.org/view/dataset/601152"}, {"dataset_uid": "601230", "doi": "10.15784/601230", "keywords": "Antarctica; Atmospheric CH4; Ch4; Glaciers/ice Sheet; Glaciers/Ice Sheet; Glaciology; Ice Core; Ice Core Chemistry; Ice Core Data; Methane; Methane Concentration; Snow/ice; Snow/Ice; South Pole; SPICEcore", "people": "Sowers, Todd A.", "repository": "USAP-DC", "science_program": "SPICEcore", "title": "South Pole CH4 data for termination", "url": "https://www.usap-dc.org/view/dataset/601230"}, {"dataset_uid": "601231", "doi": "10.15784/601231", "keywords": "Air Content; Antarctica; Glaciers/ice Sheet; Glaciers/Ice Sheet; Glaciology; Ice Core Data; Ice Core Records; Snow/ice; Snow/Ice; South Pole; SPICEcore", "people": "Sowers, Todd A.", "repository": "USAP-DC", "science_program": "SPICEcore", "title": "South Pole ice core total air content", "url": "https://www.usap-dc.org/view/dataset/601231"}, {"dataset_uid": "601517", "doi": "10.15784/601517", "keywords": "Antarctica; Argon; Argon Isotopes; Firn; Firn Temperature Gradient; Firn Thickness; Gas Isotopes; Glaciers/ice Sheet; Glaciers/Ice Sheet; Glaciology; Ice Core; Ice Core Records; Nitrogen; Nitrogen Isotopes; South Pole; SPICEcore", "people": "Severinghaus, Jeffrey P.; Morgan, Jacob", "repository": "USAP-DC", "science_program": "SPICEcore", "title": "South Pole Ice Core Isotopes of N2 and Ar", "url": "https://www.usap-dc.org/view/dataset/601517"}, {"dataset_uid": "601381", "doi": "10.15784/601381", "keywords": "Antarctica; Ch4; Glaciers/ice Sheet; Glaciers/Ice Sheet; Glaciology; Ice Core Data; Ice Core Records; Methane; South Pole; SPICEcore", "people": "Kreutz, Karl; Severinghaus, Jeffrey P.; Epifanio, Jenna; Brook, Edward J.; Buizert, Christo; Aydin, Murat; Edwards, Jon S.; Sowers, Todd A.; Kahle, Emma; Steig, Eric J.; Winski, Dominic A.; Osterberg, Erich; Fudge, T. J.; Hood, Ekaterina; Kalk, Michael; Ferris, David G.; Kennedy, Joshua A.", "repository": "USAP-DC", "science_program": "SPICEcore", "title": "South Pole ice core (SPC14) discrete methane data", "url": "https://www.usap-dc.org/view/dataset/601381"}], "date_created": "Sat, 02 Feb 2019 00:00:00 GMT", "description": "Gases trapped in ice cores have revealed astonishing things about the greenhouse gas composition of the past atmosphere, including the fact that carbon dioxide concentrations never rose above 300 parts per million during the last 800,000 years. This places today\u0027s concentration of 400 parts per million in stark contrast. Furthermore, these gas records show that natural sources of greenhouse gas such as oceans and ecosystems act as amplifiers of climate change by increasing emissions of gases during warmer periods. Such amplification is expected to occur in the future, adding to the human-produced gas burden. The South Pole ice core will build upon these prior findings by expanding the suite of gases to include, for the first time, those potent trace gases that both trapped heat and depleted ozone during the past 40,000 years. The present project on inert gases and methane in the South Pole ice core will improve the dating of this crucial record, to unprecedented precision, so that the relative timing of events can be used to learn about the mechanism of trace gas production and destruction, and consequent climate change amplification. Ultimately, this information will inform predictions of future atmospheric chemical cleansing mechanisms and climate in the context of our rapidly changing atmosphere. This award also engages young people in the excitement of discovery and polar research, helping to entrain the next generations of scientists and educators. Education of graduate students, a young researcher (Buizert), and training of technicians, will add to the nation?s human resource base. \u003cbr/\u003e \u003cbr/\u003eThis award funds the construction of the gas chronology for the South Pole 1500m ice core, using measured inert gases (d15N and d40Ar--Nitrogen and Argon isotope ratios, respectively) and methane in combination with a next-generation firn densification model that treats the stochastic nature of air trapping and the role of impurities on densification. The project addresses fundamental gaps in scientific understanding that limit the accuracy of gas chronologies, specifically a poor knowledge of the controls on ice-core d15N and the possible role of layering and impurities in firn densification. These gaps will be addressed by studying the gas enclosure process in modern firn at the deep core site. The work will comprise the first-ever firn air pumping experiment that has tightly co-located measurements of firn structural properties on the core taken from the same borehole.\u003cbr/\u003e\u003cbr/\u003eThe project will test the hypothesis that the lock-in horizon as defined by firn air d15N, CO2, and methane is structurally controlled by impermeable layers, which are in turn created by high-impurity content horizons in which densification is enhanced. Thermal signals will be sought using the inert gas measurements, which improve the temperature record with benefits to the firn densification modeling. Neon, argon, and oxygen will be measured in firn air and a limited number of deep core samples to test whether glacial period layering was enhanced, which could explain low observed d15N in the last glacial period. Drawing on separate volcanic and methane synchronization to well-dated ice cores to create independent ice and gas tie points, independent empirical estimates of the gas age-ice age difference will be made to check the validity of the firn densification model-inert gas approach to calculating the gas age-ice age difference. These points will also be used to test whether the anomalously low d15N seen during the last glacial period in east Antarctic ice cores is due to deep air convection in the firn, or a missing impurity dependence in the firn densification models. \u003cbr/\u003e\u003cbr/\u003eThe increased physical understanding gained from these studies, combined with new high-precision measurements, will lead to improved accuracy of the gas chronology of the South Pole ice core, which will enhance the overall science return from this gas-oriented core. This will lead to clarification of timing of atmospheric gas variations and temperature, and aid in efforts to understand the biogeochemical feedbacks among trace gases. These feedbacks bear on the future response of the Earth System to anthropogenic forcing. Ozone-depleting substances will be measured in the South Pole ice core record, and a precise gas chronology will add value. Lastly, by seeking a better understanding of the physics of gas entrapment, the project aims to have an impact on ice-core science in general.", "east": 0.0, "geometry": "POINT(0 -90)", "instruments": "IN SITU/LABORATORY INSTRUMENTS \u003e CORERS \u003e CORING DEVICES", "is_usap_dc": true, "keywords": "USAP-DC; AMD; LABORATORY; Antarctica; NITROGEN ISOTOPES; USA/NSF; METHANE; Amd/Us; FIELD INVESTIGATION", "locations": "Antarctica", "north": -90.0, "nsf_funding_programs": "Antarctic Glaciology; Antarctic Glaciology; Antarctic Glaciology", "paleo_time": null, "persons": "Severinghaus, Jeffrey P.; Sowers, Todd A.; Brook, Edward J.", "platforms": "LAND-BASED PLATFORMS \u003e FIELD SITES \u003e FIELD INVESTIGATION; OTHER \u003e PHYSICAL MODELS \u003e LABORATORY", "repo": "USAP-DC", "repositories": "USAP-DC", "science_programs": "SPICEcore", "south": -90.0, "title": "Collaborative Research: Inert Gas and Methane Based Climate Records throughout the South Pole Deep Ice Core", "uid": "p0010005", "west": 0.0}, {"awards": "0538049 Steig, Eric; 0538520 Thiemens, Mark", "bounds_geometry": "POINT(-112.085 -79.5)", "dataset_titles": "Multiple Isotope Analysis of Sulfate in the West Antarctic Ice Sheet Divide Ice Core; WAIS Divide sulfate and nitrate isotopes; WAIS ice core isotope data #387, 385 (full data link not provided)", "datasets": [{"dataset_uid": "002512", "doi": "", "keywords": null, "people": null, "repository": "Project website", "science_program": null, "title": "WAIS ice core isotope data #387, 385 (full data link not provided)", "url": "http://www.waisdivide.unh.edu/"}, {"dataset_uid": "609479", "doi": "10.7265/N5BG2KXH", "keywords": "Antarctica; Chemistry:ice; Chemistry:Ice; Geochemistry; Glaciers/ice Sheet; Glaciers/Ice Sheet; Ice Core Records; Paleoclimate; WAIS Divide; WAIS Divide Ice Core", "people": "Thiemens, Mark H.", "repository": "USAP-DC", "science_program": null, "title": "Multiple Isotope Analysis of Sulfate in the West Antarctic Ice Sheet Divide Ice Core", "url": "https://www.usap-dc.org/view/dataset/609479"}, {"dataset_uid": "601007", "doi": "10.15784/601007", "keywords": "Antarctica; Chemistry:ice; Chemistry:Ice; Geochemistry; Glaciers/ice Sheet; Glaciers/Ice Sheet; Glaciology; Ice Core Records; Nitrate; Oxygen Isotope; Sulfate; WAIS Divide; WAIS Divide Ice Core", "people": "Alexander, Becky; Steig, Eric J.", "repository": "USAP-DC", "science_program": "WAIS Divide Ice Core", "title": "WAIS Divide sulfate and nitrate isotopes", "url": "https://www.usap-dc.org/view/dataset/601007"}], "date_created": "Tue, 25 Apr 2017 00:00:00 GMT", "description": "0538520\u003cbr/\u003eThiemens\u003cbr/\u003eThis award supports a project to develop the first complete record of multiple isotope ratios of nitrate and sulfate covering the last ~100,000 years, from the deep ice core planned for the central ice divide of the West Antarctic Ice Sheet (WAIS). The WAIS Divide ice core will be the highest resolution long ice core obtained from Antarctica and we can expect important complementary information to be available, including accurate knowledge of past accumulation rates, temperatures, and compounds such as H2O2, CO and CH4. These compounds play significant roles in global atmospheric chemistry and climate. Especially great potential lies in the use of multiple isotope signatures. The unique mass independent fractionation (MIF) 17O signature of ozone is observed in both nitrate and sulfate, due to the interaction of their precursors with ozone. The development of methods to measure the multiple-isotope composition of small samples of sulfate and nitrate makes continuous high resolution measurements on ice cores feasible for the first time. Recent work has shown that such measurements can be used to determine the hydroxyl radial (OH) and ozone (O3) concentrations in the paleoatmosphere as well as to apportion sulfate and nitrate sources. There is also considerable potential in using these isotope measurements to quantify post depositional changes. In the first two years, continuous measurements from the upper ~100-m of ice at WAIS divide will be obtained, to provide a detailed look at seasonal through centennial scale variability. In the third year, measurements will be made throughout the available depth of the deep core (expected to reach ~500 m at this time). The broader impacts of the project include applications to diverse fields including atmospheric chemistry, glaciology, meteorology, and paleoclimatology. Because nitrate and sulfate are important atmospheric pollutants, the results will also have direct and relevance to global environmental policy. This project will coincide with the International Polar Year (2007-2008), and contributes to goals of the IPY, which include the fostering of interdisciplinary research toward enhanced understanding of atmospheric chemistry and climate in the polar regions.", "east": -112.085, "geometry": "POINT(-112.085 -79.5)", "instruments": "IN SITU/LABORATORY INSTRUMENTS \u003e SPECTROMETERS/RADIOMETERS \u003e MASS SPECTROMETERS; IN SITU/LABORATORY INSTRUMENTS \u003e SPECTROMETERS/RADIOMETERS \u003e MASS SPECTROMETERS", "is_usap_dc": true, "keywords": "Isotope Ratios; Temperature; Sulfate; West Antarctic; Paleoatmosphere; LABORATORY; Ice Core; Ice Core Data; Mass Independent Fractionation; FIELD SURVEYS; Not provided; Accumulation Rate; Oxygen Isotope; FIELD INVESTIGATION; Ice Core Chemistry; Isotope", "locations": "West Antarctic", "north": -79.5, "nsf_funding_programs": "Antarctic Glaciology; Antarctic Glaciology", "paleo_time": null, "persons": "Alexander, Becky; Steig, Eric J.; Thiemens, Mark H.", "platforms": "LAND-BASED PLATFORMS \u003e FIELD SITES \u003e FIELD INVESTIGATION; LAND-BASED PLATFORMS \u003e FIELD SITES \u003e FIELD SURVEYS; Not provided; OTHER \u003e PHYSICAL MODELS \u003e LABORATORY", "repo": "Project website", "repositories": "Project website; USAP-DC", "science_programs": "WAIS Divide Ice Core", "south": -79.5, "title": "Collaborative Research: Multiple-isotope Analysis of Nitrate and Sulfate in the West Antarctic Ice Sheet Divide Ice Core", "uid": "p0000020", "west": -112.085}, {"awards": "1043092 Steig, Eric; 1043167 White, James", "bounds_geometry": "POINT(-112.08 -79.47)", "dataset_titles": "Resampling of Deep Polar Ice Cores using Information Theory; Seasonal temperatures in West Antarctica during the Holocene ; Stable Isotopes of Ice in the Transition and Glacial Sections of the WAIS Divide Deep Ice Core; WAIS Divide Ice Core Discrete CH4 (80-3403m)", "datasets": [{"dataset_uid": "601365", "doi": "10.15784/601365", "keywords": "Antarctica; Delta 18O; Isotope; WAIS Divide; WAIS Divide Ice Core; West Antarctic Ice Sheet", "people": "White, James; Vaughn, Bruce; Garland, Joshua; Jones, Tyler R.; Morris, Valerie", "repository": "USAP-DC", "science_program": "WAIS Divide Ice Core", "title": "Resampling of Deep Polar Ice Cores using Information Theory", "url": "https://www.usap-dc.org/view/dataset/601365"}, {"dataset_uid": "601603", "doi": "10.15784/601603", "keywords": "Antarctica; Glaciers/ice Sheet; Glaciers/Ice Sheet; Glaciology; Ice Core; Ice Core Records; Seasonality; Seasonal Temperatures; Temperature; Water Isotopes; West Antarctic Ice Sheet", "people": "Jones, Tyler R.", "repository": "USAP-DC", "science_program": "WAIS Divide Ice Core", "title": "Seasonal temperatures in West Antarctica during the Holocene ", "url": "https://www.usap-dc.org/view/dataset/601603"}, {"dataset_uid": "601741", "doi": "10.15784/601741", "keywords": "Antarctica; Ch4; Glaciers/ice Sheet; Glaciers/Ice Sheet; Glaciology; Ice Core; Ice Core Records; Methane; WAIS", "people": "Sowers, Todd A.; Brook, Edward", "repository": "USAP-DC", "science_program": "WAIS Divide Ice Core", "title": "WAIS Divide Ice Core Discrete CH4 (80-3403m)", "url": "https://www.usap-dc.org/view/dataset/601741"}, {"dataset_uid": "601274", "doi": "10.15784/601274", "keywords": "Antarctica; Delta 18O; Glaciers/ice Sheet; Glaciers/Ice Sheet; Glaciology; Ice Core Records; Isotope; Snow/ice; Snow/Ice; WAIS Divide; WAIS Divide Ice Core; West Antarctic Ice Sheet", "people": "Morris, Valerie; Jones, Tyler R.; White, James; Vaughn, Bruce; Garland, Joshua; Price, Michael; Bradley, Elizabeth", "repository": "USAP-DC", "science_program": "WAIS Divide Ice Core", "title": "Stable Isotopes of Ice in the Transition and Glacial Sections of the WAIS Divide Deep Ice Core", "url": "https://www.usap-dc.org/view/dataset/601274"}, {"dataset_uid": "600169", "doi": "10.15784/600169", "keywords": "Antarctica; Geochemistry; Glaciers/ice Sheet; Glaciers/Ice Sheet; Glaciology; Ice Core Records; Isotope; Paleoclimate; Snow Accumulation; WAIS Divide; WAIS Divide Ice Core", "people": "Morris, Valerie; Jones, Tyler R.; Vaughn, Bruce; White, James", "repository": "USAP-DC", "science_program": "WAIS Divide Ice Core", "title": "Stable Isotopes of Ice in the Transition and Glacial Sections of the WAIS Divide Deep Ice Core", "url": "https://www.usap-dc.org/view/dataset/600169"}], "date_created": "Thu, 15 Sep 2016 00:00:00 GMT", "description": "Steig/1043092\u003cbr/\u003e\u003cbr/\u003eThis award supports a project to contribute one of the cornerstone analyses, stable isotopes of ice (Delta-D, Delta-O18) to the ongoing West Antarctic Ice Sheet Divide (WAIS) deep ice core. The WAIS Divide drilling project, a multi-institution project to obtain a continuous high resolution ice core record from central West Antarctica, reached a depth of 2560 m in early 2010; it is expected to take one or two more field seasons to reach the ice sheet bed (~3300 m), plus an additional four seasons for borehole logging and other activities including proposed replicate coring. The current proposal requests support to complete analyses on the WAIS Divide core to the base, where the age will be ~100,000 years or more. These analyses will form the basis for the investigation of a number of outstanding questions in climate and glaciology during the last glacial period, focused on the dynamics of the West Antarctic Ice Sheet and the relationship of West Antarctic climate to that of the Northern polar regions, the tropical Pacific, and the rest of the globe, on time scales ranging from years to tens of thousands of years. One new aspect of this work is the growing expertise at the University of Washington in climate modeling with isotope-tracer-enabled general circulation models, which will aid in the interpretation of the data. Another major new aspect is the completion and use of a high-resolution, semi-automated sampling system at the University of Colorado, which will permit the continuous analysis of isotope ratios via laser spectroscopy, at an effective resolution of ~2 cm or less, providing inter-annual time resolution for most of the core. Because continuous flow analyses of stable ice isotopes is a relatively new measurement, we will complement them with parallel measurements, every ~10-20 m, using traditional discrete sampling and analysis by mass spectrometry at the University of Washington. The intellectual merit and the overarching goal of the work are to see Inland WAIS become the reference ice isotope record for West Antarctica. The broader impacts of the work are that the data generated in this project pertain directly to policy-relevant and immediate questions of the stability of the West Antarctic ice sheet, and thus past and future changes in sea level, as well as the nature of climate change in the high southern latitudes. The project will also contribute to the development of modern isotope analysis techniques using laser spectroscopy, with applications well beyond ice cores. The project will involve a graduate student and postdoc who will work with both P.I.s, and spend time at both institutions. Data will be made available rapidly through the Antarctic Glaciological Data Center, for use by other researchers and the public.", "east": -112.08, "geometry": "POINT(-112.08 -79.47)", "instruments": null, "is_usap_dc": true, "keywords": "LABORATORY", "locations": null, "north": -79.47, "nsf_funding_programs": "Antarctic Earth Sciences; Antarctic Glaciology; Antarctic Earth Sciences; Antarctic Glaciology", "paleo_time": null, "persons": "White, James; Vaughn, Bruce; Jones, Tyler R.", "platforms": "OTHER \u003e PHYSICAL MODELS \u003e LABORATORY", "repo": "USAP-DC", "repositories": "USAP-DC", "science_programs": "WAIS Divide Ice Core", "south": -79.47, "title": "Collaborative Research: Stable Isotopes of Ice in the Transition and Glacial Sections of the WAIS Divide Deep Ice Core", "uid": "p0000078", "west": -112.08}, {"awards": "1043518 Brook, Edward", "bounds_geometry": "POINT(-112.08648 -79.46763)", "dataset_titles": "Continuous, Ultra-high Resolution WAIS-Divide Ice Core Methane Record 9.8-67.2 ka BP; Early Holocene methane records from Siple Dome, Antarctica; Methan record", "datasets": [{"dataset_uid": "601055", "doi": "10.15784/601055", "keywords": "Antarctica; Chemistry:ice; Chemistry:Ice; Geochemistry; Glaciers/ice Sheet; Glaciers/Ice Sheet; Glaciology; Ice Core Records; Methane; Paleoclimate; Siple Dome; Siple Dome Ice Core", "people": "Yang, Ji-Woong; Ahn, Jinho", "repository": "USAP-DC", "science_program": "Siple Dome Ice Core", "title": "Early Holocene methane records from Siple Dome, Antarctica", "url": "https://www.usap-dc.org/view/dataset/601055"}, {"dataset_uid": "609628", "doi": "10.7265/N5JM27K4", "keywords": "Antarctica; Chemistry:fluid; Chemistry:Fluid; Geochemistry; Glaciers/ice Sheet; Glaciers/Ice Sheet; Glaciology; Ice Core Records; Methane; Paleoclimate; WAIS Divide; WAIS Divide Ice Core", "people": "McConnell, Joseph; Rhodes, Rachel; Brook, Edward J.", "repository": "USAP-DC", "science_program": "WAIS Divide Ice Core", "title": "Continuous, Ultra-high Resolution WAIS-Divide Ice Core Methane Record 9.8-67.2 ka BP", "url": "https://www.usap-dc.org/view/dataset/609628"}, {"dataset_uid": "000176", "doi": "", "keywords": null, "people": null, "repository": "NCEI", "science_program": null, "title": "Methan record", "url": "https://www.ncdc.noaa.gov/data-access/paleoclimatology-data/datasets/ice-core"}, {"dataset_uid": "601055", "doi": "10.15784/601055", "keywords": "Antarctica; Chemistry:ice; Chemistry:Ice; Geochemistry; Glaciers/ice Sheet; Glaciers/Ice Sheet; Glaciology; Ice Core Records; Methane; Paleoclimate; Siple Dome; Siple Dome Ice Core", "people": "Ahn, Jinho; Yang, Ji-Woong", "repository": "USAP-DC", "science_program": "WAIS Divide Ice Core", "title": "Early Holocene methane records from Siple Dome, Antarctica", "url": "https://www.usap-dc.org/view/dataset/601055"}], "date_created": "Tue, 12 Jan 2016 00:00:00 GMT", "description": "1043500/Sowers\u003cbr/\u003e\u003cbr/\u003eThis award supports a project to develop a 50 yr resolution methane data set that will play a pivotal role in developing the WAIS Divide timescale as well as providing a common stratigraphic framework for comparing climate records from Greenland and West Antarctica. Even higher resolution data are proposed for key intervals to assist in precisely defining the phasing of abrupt climate change between the hemispheres. Concurrent analysis of a suit of samples from both the WAIS Divide and GISP-2 cores throughout the last 110,000 years is also proposed, to establish the interpolar methan (CH4) gradient that will be used to identify geographic areas responsible for the climate related methane emission changes. The intellectual merit of the proposed work is that it will provide chronological control needed to examine the timing of changes in climate proxies, and critical chronological ties to the Greenland ice core records via methane variations. One main objective is to understand the interpolar timing of millennial-scale climate change. This is an important scientific goal relevant to understanding climate change mechanisms in general. The proposed work will help establish a chronological framework for addressing these issues. In addition, this proposal addresses the question of what methane sources were active during the ice age, through the work on the interpolar methane gradient. This work is directed at the fundamental question of what part of the biosphere controlled past methane variations, and is important for developing more sophisticated understanding of those variations. The broader impacts of the work are that the ultra-high resolution CH4 record will directly benefit all ice core paleoclimate research and the chronological refinements will impact paleoclimate studies that rely on ice core timescales for correlation purposes. The project will support both graduate and undergraduate students and the PIs will participate in outreach to the public.", "east": -112.08648, "geometry": "POINT(-112.08648 -79.46763)", "instruments": "IN SITU/LABORATORY INSTRUMENTS \u003e PHOTON/OPTICAL DETECTORS \u003e INFRARED LASER SPECTROSCOPY", "is_usap_dc": true, "keywords": "WAIS Divide; Not provided; LABORATORY; Wais Divide-project; Methane Concentration", "locations": "WAIS Divide", "north": -79.46763, "nsf_funding_programs": "Antarctic Glaciology", "paleo_time": null, "persons": "Rhodes, Rachel; Brook, Edward J.; McConnell, Joseph", "platforms": "Not provided; OTHER \u003e PHYSICAL MODELS \u003e LABORATORY", "repo": "USAP-DC", "repositories": "NCEI; USAP-DC", "science_programs": "WAIS Divide Ice Core", "south": -79.46763, "title": "Collaborative Research: Completing an ultra-high resolution methane record from the WAIS Divide ice core", "uid": "p0000185", "west": -112.08648}, {"awards": "1245821 Brook, Edward; 1245659 Petrenko, Vasilii; 1246148 Severinghaus, Jeffrey", "bounds_geometry": "POINT(162.167 -77.733)", "dataset_titles": "Gas and Dust Measurements for Taylor Glacier and Taylor Dome Ice Cores; Last Interglacial Mean Ocean Temperature; Mean Ocean Temperature in Marine Isotope Stage 4; Measurements of 14CH4 and 14CO in ice from Taylor Glacier: Last Deglaciation; N2O Concentration and Isotope Data for 74-59 ka from Taylor Glacier, Antarctica; Taylor Glacier CO2 Isotope Data 74-59 kyr; Taylor Glacier Noble Gases - Younger Dryas; The Taylor Glacier, Antarctica, Horizontal Ice Core: Exploring changes in the Natural Methane Budget in a Warming World and Expanding the Paleo-archive", "datasets": [{"dataset_uid": "601600", "doi": "10.15784/601600", "keywords": "Antarctica; Taylor Glacier", "people": "Brook, Edward J.; Bauska, Thomas; Shackleton, Sarah; Menking, James; Severinghaus, Jeffrey P.; Dyonisius, Michael; Petrenko, Vasilii; Menking, Andy; Barker, Stephen; Buffen, Aron", "repository": "USAP-DC", "science_program": null, "title": "Taylor Glacier CO2 Isotope Data 74-59 kyr", "url": "https://www.usap-dc.org/view/dataset/601600"}, {"dataset_uid": "601260", "doi": "10.15784/601260", "keywords": "Antarctica; Carbon-14; Cosmogenic; Ice Core; Methane", "people": "Dyonisius, Michael; Petrenko, Vasilii", "repository": "USAP-DC", "science_program": "Taylor Dome Ice Core", "title": "Measurements of 14CH4 and 14CO in ice from Taylor Glacier: Last Deglaciation", "url": "https://www.usap-dc.org/view/dataset/601260"}, {"dataset_uid": "601218", "doi": "10.15784/601218", "keywords": "Antarctica; Carbon-14; Carbon Dioxide; Chemistry:ice; Chemistry:Ice; CO2; Dome C Ice Core; Epica; Epica Dome C; Geochemistry; Glaciers/ice Sheet; Glaciers/Ice Sheet; Glaciology; Ice; Ice Core Chemistry; Ice Core Data; Ice Core Gas Records; Ice Core Records; Isotope Data; Last Interglacial; Mass Spectrometer; Mass Spectrometry; Methane; Oxygen; Oxygen Isotope; Paleotemperature; Pleistocene; Snow/ice; Snow/Ice; Taylor Dome Ice Core; Taylor Glacier", "people": "Shackleton, Sarah", "repository": "USAP-DC", "science_program": "Taylor Dome Ice Core", "title": "Last Interglacial Mean Ocean Temperature", "url": "https://www.usap-dc.org/view/dataset/601218"}, {"dataset_uid": "601218", "doi": "10.15784/601218", "keywords": "Antarctica; Carbon-14; Carbon Dioxide; Chemistry:ice; Chemistry:Ice; CO2; Dome C Ice Core; Epica; Epica Dome C; Geochemistry; Glaciers/ice Sheet; Glaciers/Ice Sheet; Glaciology; Ice; Ice Core Chemistry; Ice Core Data; Ice Core Gas Records; Ice Core Records; Isotope Data; Last Interglacial; Mass Spectrometer; Mass Spectrometry; Methane; Oxygen; Oxygen Isotope; Paleotemperature; Pleistocene; Snow/ice; Snow/Ice; Taylor Dome Ice Core; Taylor Glacier", "people": "Shackleton, Sarah", "repository": "USAP-DC", "science_program": "Dome C Ice Core", "title": "Last Interglacial Mean Ocean Temperature", "url": "https://www.usap-dc.org/view/dataset/601218"}, {"dataset_uid": "601198", "doi": "10.15784/601198", "keywords": "Antarctica; Blue Ice; Chemistry:ice; Chemistry:Ice; CO2; Dust; Gas; Geochemistry; Glaciers/ice Sheet; Glaciers/Ice Sheet; Glaciology; Ice Core; Ice Core Records; Mass Spectrometer; Methane; Nitrogen Isotopes; Oxygen Isotope; Paleoclimate; Snow/ice; Snow/Ice; Taylor Dome; Taylor Dome Ice Core", "people": "Barker, Stephen; Severinghaus, Jeffrey P.; Marcott, Shaun; Shackleton, Sarah; Baggenstos, Daniel; Bauska, Thomas; Rhodes, Rachel; McConnell, Joseph; Petrenko, Vasilii; Menking, James; Brook, Edward J.; Dyonisius, Michael", "repository": "USAP-DC", "science_program": null, "title": "Gas and Dust Measurements for Taylor Glacier and Taylor Dome Ice Cores", "url": "https://www.usap-dc.org/view/dataset/601198"}, {"dataset_uid": "601398", "doi": "10.15784/601398", "keywords": "Antarctica; Glaciers/ice Sheet; Glaciers/Ice Sheet; Glaciology; Ice Core Data; Ice Core Gas Records; Ice Core Records; Marine Isotope Stage 4; MIS 4; Nitrous Oxide; Pleistocene; Taylor Dome Ice Core; Taylor Glacier", "people": "Severinghaus, Jeffrey P.; Menking, James; Brook, Edward J.; Schilt, Adrian; Shackleton, Sarah; Dyonisius, Michael; Petrenko, Vasilii", "repository": "USAP-DC", "science_program": "Taylor Dome Ice Core", "title": "N2O Concentration and Isotope Data for 74-59 ka from Taylor Glacier, Antarctica", "url": "https://www.usap-dc.org/view/dataset/601398"}, {"dataset_uid": "601176", "doi": "10.15784/601176", "keywords": "Antarctica; CO2; Glaciers/ice Sheet; Glaciers/Ice Sheet; Glaciology; Ice Core; Ice Core Records; Methane; Noble Gas; Noble Gas Isotopes; Snow/ice; Snow/Ice; Taylor Glacier; Younger Dryas", "people": "Shackleton, Sarah", "repository": "USAP-DC", "science_program": "Taylor Dome Ice Core", "title": "Taylor Glacier Noble Gases - Younger Dryas", "url": "https://www.usap-dc.org/view/dataset/601176"}, {"dataset_uid": "601415", "doi": "10.15784/601415", "keywords": "Antarctica; Glaciology; Ice Core Data; Ice Core Records; Paleoclimate; Paleotemperature; Taylor Glacier", "people": "Shackleton, Sarah", "repository": "USAP-DC", "science_program": null, "title": "Mean Ocean Temperature in Marine Isotope Stage 4", "url": "https://www.usap-dc.org/view/dataset/601415"}, {"dataset_uid": "600163", "doi": "10.15784/600163", "keywords": "Antarctica; Atmosphere; Geochemistry; Ice Core Records; Isotope; Paleoclimate; Taylor Glacier; Transantarctic Mountains", "people": "Brook, Edward J.", "repository": "USAP-DC", "science_program": null, "title": "The Taylor Glacier, Antarctica, Horizontal Ice Core: Exploring changes in the Natural Methane Budget in a Warming World and Expanding the Paleo-archive", "url": "https://www.usap-dc.org/view/dataset/600163"}], "date_created": "Mon, 13 Jul 2015 00:00:00 GMT", "description": "This award supports a project to use the Taylor Glacier, Antarctica, ablation zone to collect ice samples for a range of paleoenvironmental studies. A record of carbon-14 of atmospheric methane (14CH4) will be obtained for the last deglaciation and the Early Holocene, together with a supporting record of CH4 stable isotopes. In-situ cosmogenic 14C content and partitioning of 14C between different species (14CH4, C-14 carbon monoxide (14CO) and C-14 carbon dioxide (14CO2)) will be determined with unprecedented precision in ice from the surface down to ~67 m. Further age-mapping of the ablating ice stratigraphy will take place using a combination of CH4, CO2, \u0026#948;18O of oxygen gas and H2O stable isotopes. High precision, high-resolution records of CO2, \u0026#948;13C of CO2, nitrous oxide (N2O) and N2O isotopes will be obtained for the last deglaciation and intervals during the last glacial period. The potential of 14CO2 and Krypton-81 (81Kr) as absolute dating tools for glacial ice will be investigated. The intellectual merit of proposed work includes the fact that the response of natural methane sources to continuing global warming is uncertain, and available evidence is insufficient to rule out the possibility of catastrophic releases from large 14C-depleted reservoirs such as CH4 clathrates and permafrost. The proposed paleoatmospheric 14CH4 record will improve our understanding of the possible magnitude and timing of CH4 release from these reservoirs during a large climatic warming. A thorough understanding of in-situ cosmogenic 14C in glacial ice (production rates by different mechanisms and partitioning between species) is currently lacking. Such an understanding will likely enable the use of in-situ 14CO in ice at accumulation sites as a reliable, uncomplicated tracer of the past cosmic ray flux and possibly past solar activity, as well as the use of 14CO2 at both ice accumulation and ice ablation sites as an absolute dating tool. Significant gaps remain in our understanding of the natural carbon cycle, as well as in its responses to global climate change. The proposed high-resolution, high-precision records of \u0026#948;13C of CO2 would provide new information on carbon cycle changes both during times of rising CO2 in a warming climate and falling CO2 in a cooling climate. N2O is an important greenhouse gas that increased by ~30% during the last deglaciation. The causes of this increase are still largely uncertain, and the proposed high-precision record of N2O concentration and isotopes would provide further insights into N2O source changes in a warming world. The broader impacts of proposed work include an improvement in our understanding of the response of these greenhouse gas budgets to global warming and inform societally important model projections of future climate change. The continued age-mapping of Taylor Glacier ablation ice will add value to this high-quality, easily accessible archive of natural environmental variability. Establishing 14CO as a robust new tracer for past cosmic ray flux would inform paleoclimate studies and constitute a valuable contribution to the study of the societally important issue of climate change. The proposed work will contribute to the development of new laboratory and field analytical systems. The data from the study will be made available to the scientific community and the broad public through the NSIDC and NOAA Paleoclimatology data centers. 1 graduate student each will be trained at UR, OSU and SIO, and the work will contribute to the training of a postdoc at OSU. 3 UR undergraduates will be involved in fieldwork and research. The work will support a new, junior UR faculty member, Petrenko. All PIs have a strong history of and commitment to scientific outreach in the forms of media interviews, participation in filming of field projects, as well as speaking to schools and the public about their research, and will continue these activities as part of the proposed work. This award has field work in Antarctica.", "east": 162.167, "geometry": "POINT(162.167 -77.733)", "instruments": "IN SITU/LABORATORY INSTRUMENTS \u003e SPECTROMETERS/RADIOMETERS \u003e MASS SPECTROMETERS; IN SITU/LABORATORY INSTRUMENTS \u003e CORERS \u003e CORING DEVICES; IN SITU/LABORATORY INSTRUMENTS \u003e SPECTROMETERS/RADIOMETERS \u003e MASS SPECTROMETERS; NOT APPLICABLE \u003e NOT APPLICABLE \u003e NOT APPLICABLE", "is_usap_dc": true, "keywords": "Not provided; USAP-DC; FIELD INVESTIGATION; Stratigraphy; FIELD SURVEYS; Antarctica; Paleoenvironment; Methane; Ice Core; Carbon Dioxide; FIXED OBSERVATION STATIONS; Stable Isotopes; Ablation Zone; Taylor Glacier; Nitrous Oxide; USA/NSF; LABORATORY; AMD; Cosmogenic; Amd/Us", "locations": "Taylor Glacier; Antarctica", "north": -77.733, "nsf_funding_programs": "Antarctic Glaciology; Antarctic Glaciology; Antarctic Glaciology", "paleo_time": null, "persons": "Petrenko, Vasilii; Brook, Edward J.; Severinghaus, Jeffrey P.; PETRENKO, VASILLI", "platforms": "LAND-BASED PLATFORMS \u003e FIELD SITES \u003e FIELD INVESTIGATION; LAND-BASED PLATFORMS \u003e FIELD SITES \u003e FIELD SURVEYS; LAND-BASED PLATFORMS \u003e PERMANENT LAND SITES \u003e FIXED OBSERVATION STATIONS; Not provided; OTHER \u003e PHYSICAL MODELS \u003e LABORATORY", "repo": "USAP-DC", "repositories": "USAP-DC", "science_programs": "Taylor Dome Ice Core", "south": -77.733, "title": "Collaborative Research: The Taylor Glacier, Antarctica, Horizontal Ice Core: Exploring changes in the Natural Methane Budget in a Warming World and Expanding the Paleo-archive", "uid": "p0000283", "west": 162.167}, {"awards": "1043167 White, James; 1043092 Steig, Eric", "bounds_geometry": null, "dataset_titles": "17O excess from WAIS Divide, 0 to 25 ka BP; WAIS Divide Ice Core Discrete CH4 (80-3403m); WAIS Divide WDC06A Oxygen Isotope Record", "datasets": [{"dataset_uid": "601413", "doi": "10.15784/601413", "keywords": "Antarctica; Ice Core; Oxygen Isotope; WAIS Divide", "people": "Steig, Eric J.; Schoenemann, Spruce", "repository": "USAP-DC", "science_program": "WAIS Divide Ice Core", "title": "17O excess from WAIS Divide, 0 to 25 ka BP", "url": "https://www.usap-dc.org/view/dataset/601413"}, {"dataset_uid": "601741", "doi": "10.15784/601741", "keywords": "Antarctica; Ch4; Glaciers/ice Sheet; Glaciers/Ice Sheet; Glaciology; Ice Core; Ice Core Records; Methane; WAIS", "people": "Sowers, Todd A.; Brook, Edward", "repository": "USAP-DC", "science_program": "WAIS Divide Ice Core", "title": "WAIS Divide Ice Core Discrete CH4 (80-3403m)", "url": "https://www.usap-dc.org/view/dataset/601741"}, {"dataset_uid": "609629", "doi": "10.7265/N5GT5K41", "keywords": "Antarctica; Chemistry:fluid; Chemistry:Fluid; Geochemistry; Glaciers/ice Sheet; Glaciers/Ice Sheet; Glaciology; Ice Core Records; Isotope; Paleoclimate; WAIS Divide; WAIS Divide Ice Core", "people": "Steig, Eric J.", "repository": "USAP-DC", "science_program": "WAIS Divide Ice Core", "title": "WAIS Divide WDC06A Oxygen Isotope Record", "url": "https://www.usap-dc.org/view/dataset/609629"}], "date_created": "Sat, 06 Dec 2014 00:00:00 GMT", "description": "This award supports a project to contribute one of the cornerstone analyses, stable isotopes of ice (Delta-D, Delta-O18) to the ongoing West Antarctic Ice Sheet Divide (WAIS) deep ice core. The WAIS Divide drilling project, a multi-institution project to obtain a continuous high resolution ice core record from central West Antarctica, reached a depth of 2560 m in early 2010; it is expected to take one or two more field seasons to reach the ice sheet bed (~3300 m), plus an additional four seasons for borehole logging and other activities including proposed replicate coring. The current proposal requests support to complete analyses on the WAIS Divide core to the base, where the age will be ~100,000 years or more. These analyses will form the basis for the investigation of a number of outstanding questions in climate and glaciology during the last glacial period, focused on the dynamics of the West Antarctic Ice Sheet and the relationship of West Antarctic climate to that of the Northern polar regions, the tropical Pacific, and the rest of the globe, on time scales ranging from years to tens of thousands of years. One new aspect of this work is the growing expertise at the University of Washington in climate modeling with isotope-tracer-enabled general circulation models, which will aid in the interpretation of the data. Another major new aspect is the completion and use of a high-resolution, semi-automated sampling system at the University of Colorado, which will permit the continuous analysis of isotope ratios via laser spectroscopy, at an effective resolution of ~2 cm or less, providing inter-annual time resolution for most of the core. Because continuous flow analyses of stable ice isotopes is a relatively new measurement, we will complement them with parallel measurements, every ~10-20 m, using traditional discrete sampling and analysis by mass spectrometry at the University of Washington. The intellectual merit and the overarching goal of the work are to see Inland WAIS become the reference ice isotope record for West Antarctica. The broader impacts of the work are that the data generated in this project pertain directly to policy-relevant and immediate questions of the stability of the West Antarctic ice sheet, and thus past and future changes in sea level, as well as the nature of climate change in the high southern latitudes. The project will also contribute to the development of modern isotope analysis techniques using laser spectroscopy, with applications well beyond ice cores. The project will involve a graduate student and postdoc who will work with both P.I.s, and spend time at both institutions. Data will be made available rapidly through the Antarctic Glaciological Data Center, for use by other researchers and the public.", "east": null, "geometry": null, "instruments": "IN SITU/LABORATORY INSTRUMENTS \u003e PHOTON/OPTICAL DETECTORS \u003e INFRARED LASER SPECTROSCOPY; IN SITU/LABORATORY INSTRUMENTS \u003e CORERS \u003e CORING DEVICES; IN SITU/LABORATORY INSTRUMENTS \u003e PHOTON/OPTICAL DETECTORS \u003e INFRARED LASER SPECTROSCOPY", "is_usap_dc": true, "keywords": "AMD; ANALYTICAL LAB; USAP-DC; Amd/Us; LABORATORY; ICE CORE RECORDS; Antarctica; Wais Divide-project; FIELD SURVEYS; USA/NSF", "locations": "Antarctica", "north": null, "nsf_funding_programs": "Antarctic Earth Sciences; Antarctic Earth Sciences; Antarctic Glaciology; Antarctic Glaciology", "paleo_time": "PHANEROZOIC \u003e CENOZOIC \u003e QUATERNARY; PHANEROZOIC \u003e CENOZOIC \u003e QUATERNARY \u003e PLEISTOCENE", "persons": "Steig, Eric J.", "platforms": "LAND-BASED PLATFORMS \u003e FIELD SITES \u003e FIELD SURVEYS; OTHER \u003e PHYSICAL MODELS \u003e ANALYTICAL LAB; OTHER \u003e PHYSICAL MODELS \u003e LABORATORY", "repo": "USAP-DC", "repositories": "USAP-DC", "science_programs": "WAIS Divide Ice Core", "south": null, "title": "Collaborative Research: Stable Isotopes of Ice in the Transition and Glacial Sections of the WAIS Divide Deep Ice Core", "uid": "p0000010", "west": null}, {"awards": "0944764 Brook, Edward", "bounds_geometry": null, "dataset_titles": "Abrupt Change in Atmospheric CO2 During the Last Ice Age; High-resolution Atmospheric CO2 during 7.4-9.0 ka", "datasets": [{"dataset_uid": "609539", "doi": "10.7265/N5F47M23", "keywords": "Antarctica; Arctic; Byrd; Chemistry:fluid; Chemistry:Fluid; CO2; Geochemistry; GISP2; Glaciers/ice Sheet; Glaciers/Ice Sheet; Glaciology; Ice Core Records; Methane; Paleoclimate; Siple Dome Ice Core; Taylor Dome; Taylor Dome Ice Core", "people": "Brook, Edward J.; Ahn, Jinho", "repository": "USAP-DC", "science_program": "Byrd Ice Core", "title": "Abrupt Change in Atmospheric CO2 During the Last Ice Age", "url": "https://www.usap-dc.org/view/dataset/609539"}, {"dataset_uid": "609527", "doi": "10.7265/N5QF8QT5", "keywords": "Antarctica; Chemistry:fluid; Chemistry:Fluid; Geochemistry; Geochronology; Glaciers/ice Sheet; Glaciers/Ice Sheet; Glaciology; Ice Core Records; Paleoclimate; Siple Dome; Siple Dome Ice Core; South Pole; WAISCORES", "people": "Ahn, Jinho; Brook, Edward J.", "repository": "USAP-DC", "science_program": "Siple Dome Ice Core", "title": "High-resolution Atmospheric CO2 during 7.4-9.0 ka", "url": "https://www.usap-dc.org/view/dataset/609527"}, {"dataset_uid": "609539", "doi": "10.7265/N5F47M23", "keywords": "Antarctica; Arctic; Byrd; Chemistry:fluid; Chemistry:Fluid; CO2; Geochemistry; GISP2; Glaciers/ice Sheet; Glaciers/Ice Sheet; Glaciology; Ice Core Records; Methane; Paleoclimate; Siple Dome Ice Core; Taylor Dome; Taylor Dome Ice Core", "people": "Brook, Edward J.; Ahn, Jinho", "repository": "USAP-DC", "science_program": "Taylor Dome Ice Core", "title": "Abrupt Change in Atmospheric CO2 During the Last Ice Age", "url": "https://www.usap-dc.org/view/dataset/609539"}, {"dataset_uid": "609539", "doi": "10.7265/N5F47M23", "keywords": "Antarctica; Arctic; Byrd; Chemistry:fluid; Chemistry:Fluid; CO2; Geochemistry; GISP2; Glaciers/ice Sheet; Glaciers/Ice Sheet; Glaciology; Ice Core Records; Methane; Paleoclimate; Siple Dome Ice Core; Taylor Dome; Taylor Dome Ice Core", "people": "Brook, Edward J.; Ahn, Jinho", "repository": "USAP-DC", "science_program": "Siple Dome Ice Core", "title": "Abrupt Change in Atmospheric CO2 During the Last Ice Age", "url": "https://www.usap-dc.org/view/dataset/609539"}], "date_created": "Thu, 08 Aug 2013 00:00:00 GMT", "description": "This award supports a project to create new, unprecedented high-resolution atmospheric carbon dioxide (CO2) records spanning intervals of abrupt climate changes during the last glacial period and the early Holocene. The proposed work will utilize high-precision methods on existing ice cores from high accumulation sites such as Siple Dome and Byrd Station, Antarctica and will improve our understanding of how fast CO2 can change naturally, how its variations are linked with climate, and, combined with a coupled climate-carbon cycle model, will clarify the role of terrestrial and oceanic processes during past abrupt changes of climate and CO2. The intellectual merit of this work is that CO2 is the most important anthropogenic greenhouse gas and understanding its past variations, its sources and sinks, and how they are linked to climate change is a major goal of the climate research community. This project will produce high quality data on centennial to multi-decadal time scales. Such high-resolution work has not been conducted before because of insufficient analytical precision, slow experimental procedures in previous studies, or lack of available samples. The proposed research will complement future high-resolution studies from WAIS Divide ice cores and will provide ice core CO2 records for the target age intervals, which are in the zone of clathrate formation in the WAIS ice cores. Clathrate hydrate is a phase composed of air and ice. CO2 analyses have historically been less precise in clathrate ice than in ?bubbly ice? such as the Siple Dome ice core that will be analyzed in the proposed project. High quality, high-resolution results from specific intervals in Siple Dome that we propose to analyze will provide important data for verifying the WAIS Divide record. The broader impacts of the work are that current models show a large uncertainty of future climate-carbon cycle interactions. The results of this proposed work will be used for testing coupled carbon cycle-climate models and may contribute to reducing this uncertainty. The project will contribute to the training of several undergraduate students and a full-time technician. Both will learn analytical techniques and the basic science involved. Minorities and female students will be highly encouraged to participate in this project. Outreach efforts will include participation in news media interviews, at a local festival celebrating art, science and technology, and giving seminar presentations in the US and foreign countries. The OSU ice core laboratory has begun a collaboration with a regional science museum and is developing ideas to build an exhibition booth to make public be aware of climate change and ice core research. All data will be archived at the National Snow and Ice Data Center and at other similar archives per the OPP data policy.", "east": null, "geometry": null, "instruments": "IN SITU/LABORATORY INSTRUMENTS \u003e CHEMICAL METERS/ANALYZERS \u003e CO2 ANALYZERS; IN SITU/LABORATORY INSTRUMENTS \u003e CHEMICAL METERS/ANALYZERS \u003e GAS CHROMATOGRAPHS; IN SITU/LABORATORY INSTRUMENTS \u003e CHEMICAL METERS/ANALYZERS \u003e GAS CHROMATOGRAPHS", "is_usap_dc": true, "keywords": "GROUND-BASED OBSERVATIONS; CO2 Concentrations; Ice Core Gas Age; CO2 Uncertainty; LABORATORY; Ice Core Depth; Not provided; CH4 Concentrations", "locations": null, "north": null, "nsf_funding_programs": "Antarctic Glaciology", "paleo_time": "NOT APPLICABLE; NOT APPLICABLE", "persons": "Ahn, Jinho; Brook, Edward J.", "platforms": "LAND-BASED PLATFORMS \u003e PERMANENT LAND SITES \u003e GROUND-BASED OBSERVATIONS; Not provided; OTHER \u003e PHYSICAL MODELS \u003e LABORATORY", "repo": "USAP-DC", "repositories": "USAP-DC", "science_programs": null, "south": null, "title": "Atmospheric CO2 and Abrupt Climate Change", "uid": "p0000179", "west": null}, {"awards": "0738658 Price, P. Buford", "bounds_geometry": "POINT(112.1125 -79.4638)", "dataset_titles": "Access to data; data from one of three optical logs we made at WAIS Divide; WAIS Divide Laser Dust Logger Data", "datasets": [{"dataset_uid": "001349", "doi": "", "keywords": null, "people": null, "repository": "PI website", "science_program": null, "title": "Access to data", "url": "http://icecube.berkeley.edu/~bay/wdc/"}, {"dataset_uid": "609540", "doi": "10.7265/N5C53HSG", "keywords": "Antarctica; Atmosphere; Chemistry:ice; Chemistry:Ice; Dust; Glaciers/ice Sheet; Glaciers/Ice Sheet; Glaciology; Ice Core Records; Laser Dust Logger; WAIS Divide Ice Core", "people": "Bay, Ryan", "repository": "USAP-DC", "science_program": "WAIS Divide Ice Core", "title": "WAIS Divide Laser Dust Logger Data", "url": "https://www.usap-dc.org/view/dataset/609540"}, {"dataset_uid": "000188", "doi": "", "keywords": null, "people": null, "repository": "USAP-DC", "science_program": null, "title": "data from one of three optical logs we made at WAIS Divide", "url": "http://icecube.berkeley.edu/~bay/wdc/"}], "date_created": "Tue, 19 Jun 2012 00:00:00 GMT", "description": "This award supports a project to use two new scanning fluorimeters to map microbial concentrations vs depth in the WAIS Divide ice core as portions of it become available at NICL, and selected portions of the GISP2 ice core for inter-hemispheric comparison. Ground-truth calibrations with microbes in ice show that the instruments are sensitive to a single cell and can scan the full length of a 1-meter core at 300-micron intervals in two minutes. The goals of these studies will be to exploit the discovery that microbes are transported onto ice, in clumps, several times per year and that at rare intervals (not periodically) of ~104 years, a much higher flux, sometimes lasting \u003e1 decade, reaches the ice. From variations ranging from seasonal to millennial to glacial scale in the arrival time distribution of phototrophs, methanogens, and total microbes in the Antarctic and Arctic ice, the investigators will attempt to determine oceanic and terrestrial sources of these microbes and will look for correlations of microbial bursts with dust concentration and temperature proxies. In addition the project will follow up on the discovery that the rare instances of very high microbial flux account for some of the\"gas artifacts\" in ice cores - isolated spikes of excess CH4 and N2O that have been discarded by others in previous climate studies. The intellectual merit of this project is that it will exploit scanning fluorimetry of microbes as a powerful new tool for studies ranging from meteorology to climatology to biology, especially when combined with mapping of dust, gases, and major element chemistry in ice cores. In 2010-11 the WAIS Divide borehole will be logged with the latest version of the dust logger. The log will provide mm-scale depth resolution of dust concentration and of volcanic ash layers down the entire depth of the borehole. The locations of ash layers in the ice will be determined and chemical analyses of the ash will be analyzed in order to determine provenance. By comparing data from the WAIS Divide borehole with data from other boreholes and with chemical data (obtained by others) on volcanic layers, the researchers will examine the relationship between the timing of volcanic eruptions and abrupt climate change. Results from this project with the scanning fluorimeters and the dust logger could have applications to planetary missions, borehole oceanography, limnology, meteorology, climate, volcanology, and ancient life in ice. A deeper understanding of the causes of abrupt climate change, including a causal relationship with volcanic explosivity, would enable a better understanding of the adverse effects on climate. The broader impact of the project is that it will provide training to students and post-docs from the U. S. and other countries.", "east": 112.1125, "geometry": "POINT(112.1125 -79.4638)", "instruments": "IN SITU/LABORATORY INSTRUMENTS \u003e RECORDERS/LOGGERS \u003e OPTICAL DUST LOGGERS; IN SITU/LABORATORY INSTRUMENTS \u003e RECORDERS/LOGGERS \u003e OPTICAL DUST LOGGERS; IN SITU/LABORATORY INSTRUMENTS \u003e CHEMICAL METERS/ANALYZERS \u003e FLUOROMETERS", "is_usap_dc": true, "keywords": "Dust Loggers; Dust Concentration; Ice Core; West Antarctic Ice Sheet; LABORATORY; Microbial; Fluorimetry; GROUND-BASED OBSERVATIONS; Meteorology; Climatologymeteorologyatmosphere; Ice", "locations": "West Antarctic Ice Sheet", "north": -79.4638, "nsf_funding_programs": "Antarctic Glaciology", "paleo_time": null, "persons": "Bay, Ryan; Price, Buford; Souney, Joseph Jr.", "platforms": "LAND-BASED PLATFORMS \u003e PERMANENT LAND SITES \u003e GROUND-BASED OBSERVATIONS; OTHER \u003e PHYSICAL MODELS \u003e LABORATORY", "repo": "PI website", "repositories": "PI website; USAP-DC", "science_programs": "WAIS Divide Ice Core", "south": -79.4638, "title": "Climatology, Meteorology, and Microbial Metabolism in Ice with Dust Loggers and Fluorimetry", "uid": "p0000009", "west": 112.1125}, {"awards": "0538578 Brook, Edward; 0538538 Sowers, Todd", "bounds_geometry": null, "dataset_titles": "Late Holocene Methane Concentrations from WAIS Divide and GISP2; Methane Concentrations from the WAIS Divide Ice Core (WDC06A), 60 to 11,300 ybp; The Antarctic Glaciological Data Center (AGDC) at the National Snow and Ice Data Center (NSIDC) archives and distributes Antarctic glaciological and cryospheric system data collected by the U.S. Antarctic Program.", "datasets": [{"dataset_uid": "001303", "doi": "", "keywords": null, "people": null, "repository": "NSIDC", "science_program": null, "title": "The Antarctic Glaciological Data Center (AGDC) at the National Snow and Ice Data Center (NSIDC) archives and distributes Antarctic glaciological and cryospheric system data collected by the U.S. Antarctic Program.", "url": "https://nsidc.org/data/agdc"}, {"dataset_uid": "609509", "doi": "10.7265/N5J1013R", "keywords": "Antarctica; Atmosphere; Chemistry:fluid; Chemistry:Fluid; Geochemistry; Glaciers/ice Sheet; Glaciers/Ice Sheet; Ice Core Records; Methane; Paleoclimate; WAIS Divide; WAIS Divide Ice Core", "people": "Sowers, Todd A.", "repository": "USAP-DC", "science_program": "WAIS Divide Ice Core", "title": "Methane Concentrations from the WAIS Divide Ice Core (WDC06A), 60 to 11,300 ybp", "url": "https://www.usap-dc.org/view/dataset/609509"}, {"dataset_uid": "609586", "doi": "10.7265/N5W66HQQ", "keywords": "Antarctica; Arctic; Chemistry:fluid; Chemistry:Fluid; Geochemistry; GISP2; Glaciers/ice Sheet; Glaciers/Ice Sheet; Glaciology; Ice Core Records; Methane; Paleoclimate; WAIS Divide; WAIS Divide Ice Core", "people": "Mitchell, Logan E", "repository": "USAP-DC", "science_program": "WAIS Divide Ice Core", "title": "Late Holocene Methane Concentrations from WAIS Divide and GISP2", "url": "https://www.usap-dc.org/view/dataset/609586"}], "date_created": "Thu, 19 Apr 2012 00:00:00 GMT", "description": "Sowers/Brook\u003cbr/\u003e0538538\u003cbr/\u003eThis award supports a project to develop a high-resolution (every 50 yr) methane data set that will play a pivotal role in developing the timescale for the new deep ice core being drilled at the West Antarctic Ice Sheet Divide (WAIS Divde) site as well as providing a common stratigraphic framework for comparing climate records from Greenland and WAIS Divide. Certain key intervals will be measured at even higher resolution to assist in precisely defining the phasing of abrupt climate change between the northern and southern hemispheres. Concurrent analysis of a suit of samples from both the WAIS Divide and GISP2 ice cores throughout the last 110kyr is also proposed, to establish the inter-hemispheric methane gradient which will be used to identify geographic areas responsible for the climate-related methane emission changes. A large gas measurement inter-calibration of numerous laboratories, utilizing both compressed air cylinders and WAIS Divide ice core samples, will also be performed. The intellectual merit of the proposed work is that it will provide the chronological control needed to examine the timing of changes in climate proxies, and critical chronological ties to the Greenland ice core records via methane variations. In addition, the project addresses the question of what methane sources were active during the ice age and will help to answer the fundamental question of what part of the biosphere controlled past methane variations. The broader impact of the proposed work is that it will directly benefit all ice core paleoclimate research and will impact the paleoclimate studies that rely on ice core timescales for correlation purposes. The project will also support a Ph.D. student at Oregon State University who will have the opportunity to be involved in a major new ice coring effort with international elements. Undergraduates at Penn State will gain valuable laboratory experience and participate fully in the project. The proposed work will underpin the WAIS Divide chronology, which will be fundamental to all graduate student projects that involve the core. The international inter-calibration effort will strengthen ties between research institutions on four continents and will be conducted as part of the International Polar Year research agenda.", "east": null, "geometry": null, "instruments": "IN SITU/LABORATORY INSTRUMENTS \u003e CHEMICAL METERS/ANALYZERS \u003e GAS CHROMATOGRAPHS; IN SITU/LABORATORY INSTRUMENTS \u003e CHEMICAL METERS/ANALYZERS \u003e GAS CHROMATOGRAPHS", "is_usap_dc": true, "keywords": "Antarctica; Ch4; West Antarctica; Wais Divide-project; GROUND-BASED OBSERVATIONS; FIELD INVESTIGATION; FIELD SURVEYS; Methane Concentration; Methane; Ice Core; WAIS Divide; Antarctic; LABORATORY", "locations": "Antarctic; WAIS Divide; Antarctica; West Antarctica", "north": null, "nsf_funding_programs": "Antarctic Organisms and Ecosystems; Antarctic Glaciology; Antarctic Glaciology", "paleo_time": "PHANEROZOIC \u003e CENOZOIC \u003e QUATERNARY \u003e HOLOCENE; NOT APPLICABLE; PHANEROZOIC \u003e CENOZOIC \u003e QUATERNARY \u003e HOLOCENE", "persons": "Lee, James; Buizert, Christo; Brook, Edward J.; Mitchell, Logan E; Sowers, Todd A.", "platforms": "LAND-BASED PLATFORMS \u003e FIELD SITES \u003e FIELD INVESTIGATION; LAND-BASED PLATFORMS \u003e FIELD SITES \u003e FIELD SURVEYS; LAND-BASED PLATFORMS \u003e PERMANENT LAND SITES \u003e GROUND-BASED OBSERVATIONS; OTHER \u003e PHYSICAL MODELS \u003e LABORATORY", "repo": "NSIDC", "repositories": "NSIDC; USAP-DC", "science_programs": "WAIS Divide Ice Core", "south": null, "title": "Collaborative Research: Constructing an Ultra-high Resolution Atmospheric Methane Record for the Last 140,000 Years from WAIS Divide Core.", "uid": "p0000025", "west": null}, {"awards": "0739491 Sowers, Todd; 0739598 Aydin, Murat", "bounds_geometry": null, "dataset_titles": "Alkanes in Firn Air Samples, Antarctica and Greenland; Methane Isotopes in South Pole Firn Air, 2008", "datasets": [{"dataset_uid": "609502", "doi": "10.7265/N55T3HFP", "keywords": "Antarctica; Atmosphere; Chemistry:fluid; Chemistry:Fluid; Geochemistry; Isotope; Paleoclimate; Snow/ice; Snow/Ice; South Pole", "people": "Sowers, Todd A.", "repository": "USAP-DC", "science_program": null, "title": "Methane Isotopes in South Pole Firn Air, 2008", "url": "https://www.usap-dc.org/view/dataset/609502"}, {"dataset_uid": "609504", "doi": "10.7265/N5X9287C", "keywords": "Antarctica; Arctic; Atmosphere; Chemistry:fluid; Chemistry:Fluid; Geochemistry; Glaciers/ice Sheet; Glaciers/Ice Sheet; Greenland; Snow/ice; Snow/Ice; South Pole; WAIS Divide", "people": "Saltzman, Eric; Aydin, Murat", "repository": "USAP-DC", "science_program": null, "title": "Alkanes in Firn Air Samples, Antarctica and Greenland", "url": "https://www.usap-dc.org/view/dataset/609504"}], "date_created": "Thu, 18 Aug 2011 00:00:00 GMT", "description": "This award supports a project to make measurements of methane and other trace gases in firn air collected at South Pole, Antarctica. The analyses will include: methane isotopes (delta-13CH4 and delta-DCH4), light non-methane hydrocarbons (ethane, propane, and n-butane), sulfur gases (COS, CS2), and methyl halides (CH3Cl and CH3Br). The atmospheric burdens of these trace gases reflect changes in atmospheric OH, biomass burning, biogenic activity in terrestrial, oceanic, and wetland ecosystems, and industrial/agricultural activity. The goal of this project is to develop atmospheric histories for these trace gases over the last century through examination of depth profiles of these gases in South Pole firn air. The project will involve two phases: 1) a field campaign at South Pole, Antarctica to drill two firn holes and fill a total of ~200 flasks from depths reaching 120 m, 2) analysis of firn air at University of California, Irvine, Penn State University, and several other collaborating laboratories. Atmospheric histories will be inferred from the measurements using a one dimensional advective/diffusive model of firn air transport. This study will provide new information about the recent changes in atmospheric levels of these gases, providing about a 90 year long time series record that connects the earlier surface and firn air measurements to present day. The project will also explore the possibility of in- situ production of light non-methane hydrocarbons in firn air that is relevant to the interpretation of ice core records. The broader impacts of this research are that it has the potential for significant societal impact by improving our understanding of climate change and man\u0027s input to the atmosphere. The results of this work will be disseminated through the peer review process, and will contribute to environmental assessments, such as the Inter-governmental Panel on Climate Change (IPCC) Climate Assessment and the Word Meteorological Organization (WMO) Stratospheric Ozone Assessment. This research will provide educational opportunities for graduate and undergraduate students, and will contribute to a teacher training program for K-12 teachers in minority school districts.", "east": null, "geometry": null, "instruments": "IN SITU/LABORATORY INSTRUMENTS \u003e CHEMICAL METERS/ANALYZERS \u003e GAS CHROMATOGRAPHS; IN SITU/LABORATORY INSTRUMENTS \u003e SPECTROMETERS/RADIOMETERS \u003e MASS SPECTROMETERS; IN SITU/LABORATORY INSTRUMENTS \u003e CHEMICAL METERS/ANALYZERS \u003e GC-MS", "is_usap_dc": true, "keywords": "FIELD INVESTIGATION; Isotope; Firn Air Chemistry; Firn Air Isotope Measurements; Not provided; LABORATORY; South Pole; Firn; Delta 13C; Carbon-13; Mass Spectrometer; Deuterium; Mass Spectrometry; Firn Air Samples; Carbon; Gas Chromatography; Polar Firn Air; GROUND-BASED OBSERVATIONS; Methane; Antarctica; Firn Air Isotopes; Delta Deuterium; FIELD SURVEYS; Firn Air; Chromatography; Methane Isotopes; Carbon Isotopes; Stable Isotopes", "locations": "Antarctica; South Pole", "north": null, "nsf_funding_programs": "Antarctic Glaciology; Antarctic Glaciology", "paleo_time": null, "persons": "Aydin, Murat; Saltzman, Eric; Sowers, Todd A.", "platforms": "LAND-BASED PLATFORMS \u003e FIELD SITES \u003e FIELD INVESTIGATION; LAND-BASED PLATFORMS \u003e FIELD SITES \u003e FIELD SURVEYS; LAND-BASED PLATFORMS \u003e PERMANENT LAND SITES \u003e GROUND-BASED OBSERVATIONS; Not provided; OTHER \u003e PHYSICAL MODELS \u003e LABORATORY", "repo": "USAP-DC", "repositories": "USAP-DC", "science_programs": null, "south": null, "title": "Collaborative Research: Methane Isotopes, Hydrocarbons, and other Trace Gases in South Pole Firn Air", "uid": "p0000162", "west": null}, {"awards": "0126194 Harder, Susan", "bounds_geometry": null, "dataset_titles": "Access to data", "datasets": [{"dataset_uid": "001336", "doi": "", "keywords": null, "people": null, "repository": "NSIDC", "science_program": null, "title": "Access to data", "url": "http://nsidc.org/data/agdc_investigators.html"}], "date_created": "Tue, 20 Feb 2007 00:00:00 GMT", "description": "This award supports a two-year project to continue work developing the techniques to make carbon monoxide (CO) measurements in ice core samples. Carbon monoxide is an important atmospheric chemical constituent as it is a primary sink for hydroxyl radical (OH) (and therefore influences the oxidizing capacity of the atmosphere) and because the concentrations of three major greenhouses gases , carbon dioxide (CO2), methane (CH4) and ozone (O3) are directly tied to the concentration of CO. In light of recent anthropogenic increases in the emissions of CO, CO2, CH4 and NOx, it is desirable to understand this complex chemical system and the changes in the greenhouse forcing resulting from perturbation. Because it is difficult to test the accuracy of models for past and future conditions for which no direct atmospheric measurements of trace gas concentrations are available these measurements must be obtained in other ways. Polar ice cores provide a means to make these measurements. Further work is necessary to refine the analytical technique and additional measurements are necessary to investigate the accuracy of these results and to establish the nature of temporal trends in CO. It is anticipated that the CO record, combined with existing or new data for CO2, CH4 , N2O and other paleoclimate variables, will provide further constraints on model studies of the effect of changing atmospheric chemistry on greenhouse forcing.", "east": null, "geometry": null, "instruments": "IN SITU/LABORATORY INSTRUMENTS \u003e CORERS \u003e CORING DEVICES; IN SITU/LABORATORY INSTRUMENTS \u003e CHEMICAL METERS/ANALYZERS \u003e GAS CHROMATOGRAPHS", "is_usap_dc": false, "keywords": "Not provided", "locations": null, "north": null, "nsf_funding_programs": "Antarctic Glaciology", "paleo_time": "PHANEROZOIC \u003e CENOZOIC \u003e QUATERNARY \u003e HOLOCENE", "persons": "Harder, Susan", "platforms": "Not provided", "repo": "NSIDC", "repositories": "NSIDC", "science_programs": null, "south": null, "title": "Ice Core Records of Atmospheric Carbon Monoxide", "uid": "p0000706", "west": null}, {"awards": "0125900 Sowers, Todd", "bounds_geometry": "POINT(-148.8 -81.7)", "dataset_titles": null, "datasets": null, "date_created": "Thu, 26 May 2005 00:00:00 GMT", "description": "0125900\u003cbr/\u003eSowers\u003cbr/\u003e\u003cbr/\u003eThis award supports a project to improve the understanding of the biogeochemical processes that control CH4 emissions. Records of the concentration of methane in trapped gases in ice tell us about changes in atmospheric loading through time. Such records do not, however, provide information on the individual sources or sinks. One way to refine our understanding of the cycling of bioactive trace gases like methane is to use stable isotope records of trapped gases in ice cores. This project will measure the Deuterium/Hydrogen (D/H) ratio of methane trapped in shallow/recent ice (covering the last ~ 200 years) at Siple Dome, Antarctica. The proposed work will complement current efforts to measure the carbon-13 isotope ratio of methane in ice cores and will provide fundamental information on the various sources and sinks of atmospheric methane over the last 200 years.", "east": -148.8, "geometry": "POINT(-148.8 -81.7)", "instruments": null, "is_usap_dc": false, "keywords": "Siple Dome; Not provided; Ch4; Methane; Antarctica; Ice Core", "locations": "Siple Dome; Antarctica", "north": -81.7, "nsf_funding_programs": "Antarctic Glaciology", "paleo_time": null, "persons": "Sowers, Todd A.", "platforms": "Not provided", "repositories": null, "science_programs": null, "south": -81.7, "title": "Constructing the first D/H record of atmospheric methane covering the last two centuries.", "uid": "p0000754", "west": -148.8}]

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